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Ionic Liquors
Ionic liquids are excellent substitutes for
traditional organic solvents in many typical organic reactions, often
producing higher selectivities as well as higher yields, and enhancing
the reaction rate. Additionally, they can serve as catalyst
immobilization for the easy recycling of homogeneous catalysts without
need for special function, and have been successfully employed
as electrolytes in electro-chemistry. "Tailor-made" solvents
(optimization of the ionic liquid's characteristics) can be achieved
through a broad choice of anion and cation combinations.
Ionic
liquids are attractive solvents as they are non-volatile,
non-flammable, have a high thermal stability and are relatively
inexpensive to manufacture. They usually exist as liquids well below
room temperature up to a temperature as high as 200oC.
The
key point about ionic liquids is that they are liquid salts, which
means they consist of a salt that exists in the liquid phase. They are
not simply salts dissolved in liquid. Usually one or both of the ions
is particularly large and the cation has a low degree of symmetry,
these factors result in ionic liquids having a reduced lattice energy
and hence lower melting points.Many ionic liquids have even been
developed for specific synthetic problems. For this reason, ionic
liquids have been termed "designer solvents".
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